Microstructure and synthesis mechanism of Al-Ti-C-Sr master alloy
(School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450002, China)
Abstract: Al-5Ti-0.5C-8Sr (mass fraction, %) master alloy was prepared using a melt reaction method. The microstructure and synthetic process of the master alloy were investigated by optical microscopy, X-ray diffraction, scanning electron microscopy and X-ray energy-dispersive spectrum. The results show that the master alloy is composed of α(Al), TiAl3, TiC, Al4Sr and Al-Ti-Sr phases. The synthesis mechanisms of the master alloy are as follows: TiAl3 is formed through the reaction between K2TiF6 and Al melt at 850 ℃; when the melt was heated up to 1 200−1 300 ℃, TiC was formed through the reaction: Ti+C(s)=TiC(s); Al4Sr was formed through the binary uniform reaction when Sr was added into the melt; after the following solidification process in the peritectic reaction: L(Al, Sr)+α(TiAl3)→β(Al-Ti-Sr), the enwrapped structure was formed with the outer layer of Al-Ti-Sr phase and the internal layer of TiAl3 phase.
Key words: Al-Ti-C-Sr alloy; synthesis mechanism; microstructure; Al-Ti-Sr phase