Effects of Ce on microstructure of semi-continuously cast Mg-1.5Zn-0.2Zr magnesium alloy ingots
(1. College of Materials Science and Engineering, Chongqing University, Chongqing 400045, China;
2. National Engineering Research Center for Magnesium Alloys, Chongqing University, Chongqing, 400044, China)
2. National Engineering Research Center for Magnesium Alloys, Chongqing University, Chongqing, 400044, China)
Abstract: Mg-1.5Zn-0.2Zr-xCe (x=0, 0.1, 0.3, 0.5, mass fraction, %) alloys were prepared by conventional semi-continuous casting. The effect of rare earth Ce on the microstructure of Mg-1.5Zn-0.2Zr-xCe alloys was studied and the distribution of Ce was analyzed by optical microscopy (OM), X-ray diffractometry (XRD) and scanning electron microscopy (SEM). The results indicate that Ce element exists in the form of Mg12Ce phase and has an obvious refining effect on the microstructure of test alloys. As the Ce content increases, the grain size reduces, the grain boundaries turn thinner, and the distribution of Mg12Ce precipitates becomes more and more dispersed. The Mg-1.5Zn-0.2Zr alloy with 0.3%Ce has the best refinement effect. From center to periphery of the ingot, the amount of granular precipitates in the grain reduces. In longitudinal section of the ingot, some relative long columnar grains appear.
Key words: Mg-1.5Zn-0.2Zr alloy; Ce; semi-continuous casting; refinement