Effects of reaction parameters on preparation of Cu nanoparticles via aqueous solution reduction method with NaBH4
(1. School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China;
2. Department of Materials Science, Graduate School of Engineering, Nagoya University, Nagoya 4648603, Japan)
2. Department of Materials Science, Graduate School of Engineering, Nagoya University, Nagoya 4648603, Japan)
Abstract: The preparation of Cu nanoparticles by the aqueous solution reduction method was investigated. The effects of different reaction parameters on the preparation of Cu nanoparticles were studied. The optimum conditions for preparing well-dispersed nanoparticles were found as follows: 0.4 mol/L NaBH4 was added into solution containing 0.2 mol/L Cu2+, 1.0% gelatin dispersant in mass fraction, and 1.2 mol/L NH3·H2O at pH 12 and 313 K. In addition, a series of experiments were performed to discover the reaction process. NH3·H2O was found to be able to modulate the reaction process. At pH=10, Cu2+ was transformed to Cu(NH3)42+ as precursor after the addition of NH3·H2O, and then Cu(NH3)42+ was reduced by NaBH4 solution. At pH=12, Cu2+ was transformed to Cu(OH)2 as precursor after the addition of NH3·H2O, and Cu(OH)2 was then reduced by NaBH4 solution.
Key words: Cu nanoparticles; NaBH4; Cu(OH)2; Cu(NH3)42+; aqueous solution reduction method; precursor; reaction process