Solvent impregnated resin prepared using ionic liquid Cyphos IL 104 for Cr(VI) removal
(1. School of Chemistry and Environmental Engineering, Changchun University of Science and Technology,
Changchun 130022, China;
2. State Key Laboratory of Rare Earth Resources Utilization, Changchun Institute of Applied Chemistry,
Chinese Academy of Sciences, Changchun 130022, China;
3. University of Chinese Academy of Sciences, Beijing 100039, China)
Changchun 130022, China;
2. State Key Laboratory of Rare Earth Resources Utilization, Changchun Institute of Applied Chemistry,
Chinese Academy of Sciences, Changchun 130022, China;
3. University of Chinese Academy of Sciences, Beijing 100039, China)
Abstract: Ionic liquid (IL) trihexyl (tetradecyl) phosphonium bis 2,4,4-trimethylpentylphosphinate (Cyphos IL 104) was impregnated on XAD-7 resin. The solvent impreganated resin (SIR) was prepared and applied in Cr(VI) removal. The morphology and the thermal stability of the resins were explored. The effects of equilibrium time and initial pH value on Cr(VI) adsorption were investigated. Adsorption isotherm, separation and desorption of the SIR, and selectivity of SIR were also explored. The results show that Cyphos IL 104 exists in the inner XAD-7 resin, and the optimum pH value range of the SIR for Cr(VI) extraction is 0 to 2. When NaOH used as desorption solution, the Cr(VI) can be effectively desorbed from the SIR.
Key words: solid-liquid extraction; Cyphos IL 104; Cr(VI); resin; adsorption isotherm; separation; desorption