Efficient destruction of sodium cyanide by thermal decomposition with addition of ferric oxide
(1. School of Metallurgy, Northeastern University, Shenyang 110819, China;
2. CSIRO Minerals Resources, Clayton, Victoria 3168, Australia;
3. School of Resources and Civil Engineering, Northeastern University, Shenyang 110819, China;
4. Science and Technology Innovation Center of Smart Water and Resource Environment, Northeastern University, Shenyang 110819, China)
2. CSIRO Minerals Resources, Clayton, Victoria 3168, Australia;
3. School of Resources and Civil Engineering, Northeastern University, Shenyang 110819, China;
4. Science and Technology Innovation Center of Smart Water and Resource Environment, Northeastern University, Shenyang 110819, China)
Abstract: Efficient destruction of cyanide by thermal decomposition with ferric oxide addition was proposed. The mechanism of destruction of sodium cyanide with or without ferric oxide addition under various conditions was examined by XRD, DSC-TG, and chemical analysis technologies. In the absence of ferric oxide, sodium cyanide decomposes at 587.4 °C in air and 879.2 °C in argon atmosphere. In the presence of ferric oxide, about 60% of sodium cyanide decomposes at 350 °C for 30 min in argon, while almost all sodium cyanide decomposes within 30 min in air or O2 with mass ratio of ferric oxide to sodium cyanide of 1:1. The increase of ferric oxide addition, temperature, and heating time facilitates the destruction of sodium cyanide. It is believed that with ferric oxide addition, NaCN reacts with Fe2O3 to form Na4Fe(CN)6, Na2CO3, NaNO2 and Fe3O4 in argon. NaCN decomposes into NaCNO, Na4Fe(CN)6, minor NaNO2, and the formed NaCNO and Na4Fe(CN)6 further decompose into Na2CO3, CO2, N2, FeOx, and minor NOx in air or O2.
Key words: cyanide destruction; thermal decomposition; ferric oxide; catalytic oxidation; sodium cyanide