Corrosion properties of ECAP-processed Mg-Al-Ca-Mn alloys with separate Al2Ca and Mg2Ca phases
(1. College of Mechanics and Materials, Hohai University, Nanjing 210000, China;
2. School of Materials Science and Engineering, Tianjin University, Tianjin 300350, China;
3. School of Materials Science and Engineering, Southeast University, Nanjing 211189, China;
4. School of Mechanical Engineering, Yangzhou University, Yangzhou 225127, China;
5. Jiangsu Key Laboratory for Light Metal Alloys, Nanjing Yunhai Special Metals Co., Ltd., Nanjing 211200, China)
2. School of Materials Science and Engineering, Tianjin University, Tianjin 300350, China;
3. School of Materials Science and Engineering, Southeast University, Nanjing 211189, China;
4. School of Mechanical Engineering, Yangzhou University, Yangzhou 225127, China;
5. Jiangsu Key Laboratory for Light Metal Alloys, Nanjing Yunhai Special Metals Co., Ltd., Nanjing 211200, China)
Abstract: To investigate the effect of separate Al2Ca and Mg2Ca phases on the corrosion properties of Mg-Al-Ca-Mn alloys, OM, SEM, immersion and electrochemical tests were conducted on the as-cast and ECAP Al2Ca-containing (2Ca) and Mg2Ca-containing (4Ca) alloys. At the beginning of corrosion, the two as-cast alloys are corroded slowly compared with ECAP alloys. With prolonging the corrosion time, the corrosion of ECAP alloys becomes slighter than that of as-cast alloys, which is mainly ascribed to the dispersion and refinement of the second phase in ECAP alloys. Moreover, the corrosion degree of 2Ca alloys is always slighter than that of 4Ca alloys, suggesting that Al2Ca phase is more beneficial to the enhancement of corrosion resistance of Mg-Al-Ca-Mn based alloys than Mg2Ca phase. Finally, based on the examinations of corrosion surface and electrochemical testing results, different corrosion mechanisms caused by the distributions and morphology of Al2Ca and Mg2Ca phases are discussed.
Key words: Mg-Al-Ca-Mn alloy; equal channel angular pressing; second phase; refinement; corrosion properties