Thermodynamic investigation of Fe-Ti-Y ternary system
(State Key Laboratory for Powder Metallurgy, Central South University, Changsha 410083, China)
Abstract: An extensive investigation on the Fe-Ti-Y system was performed via experimental measurement and thermodynamic calculation. The Fe-Ti-Y ternary couples at 1 273 K were prepared with a desire to provide accurate phase relationships needed for the refinement of this ternary phase diagram. And a tentative isothermal section of Fe-Ti-Y at 1 273 K was built based on the experimental information. In the thermodynamic modeling, the thermodynamic parameters for the Ti-Y binary system and the ternary phase in the Fe-Ti-Y system were evaluated. Those for the Fe-Ti and Fe-Y systems from literature were slightly modified for the compatibility. The isothermal sections of Fe-Ti-Y ternary system at 873 K and 1 273 K were calculated. The ternary compound Fe11TiY and Fe2(Ti, Y) solid solution formed from Fe2Ti and Fe2Y are detected, which is in good agreement with the literature information.
Key words: Fe-Ti-Y; thermodynamic calculation; Fe11TiY; diffusion couple