Electrochemical behaviors of anodic alumina sealed by Ce-Mo in NaCl solutions
(School of Materials Science and Engineering,
Beijing University of Chemical Technology, Beijing 100029, China)
Beijing University of Chemical Technology, Beijing 100029, China)
Abstract: The elimination of toxic materials in sealing methods for anodic films on 1070 aluminum alloy was studied. The new process uses chemical treatments in cerium solution and an electrochemical treatment in a molybdate solution. Potentiodynamic polarization and electrochemical impedance spectroscopy(EIS) were used to study the influences of sealing methods on the corrosion behavior of anodic films in NaCl solutions. The results show that the Ce-Mo sealing makes the surface structure and morphology of anodic films uniform and compact. Ce and Mo produce a cooperative effect to improve the corrosion resistance of anodic films. Anodic films sealed by Ce-Mo provide high corrosion resistance both in acidic and basic solutions.
Key words: 1070 aluminum alloy; anodic film; sealing; electrochemical impedance spectroscopy