Effect of Lix984N content on phase disengagement dynamics in copper-SX
(1. Department of Materials, Shanghai Institute of Technology,
Shanghai 200233, China;
2. School of Resource Processing and Bioengineering,
Central South University, Changsha 410083, China)
Shanghai 200233, China;
2. School of Resource Processing and Bioengineering,
Central South University, Changsha 410083, China)
Abstract: Lix984N is intimately related to the dynamic characteristics of phase disengagement in copper solvent extraction because of its interfacial activity. With increasing Lix984N content, the phase disengagement time is prolonged and the mechanism dominating phase disengagement process transfers from sedimentation to coalescence. The rate of droplet coalescence is faster than that of droplet sedimentation in the dense dispersion band when the volume fraction of Lix984N is less than 3.0%. The former almost equaled to the latter at Lix984N content of 3.0% and finally becomes lower than the latter when the volume fraction of Lix984N is more than 3.0%. The relationship between the adhesion force of two equal droplets and physical properties of fluids is deduced, which explains that the change of physical properties of organic phase with Lix984N content can make droplet coalescence more difficult and phase disengagement slower.
Key words: copper solvent extraction; phase disengagement; hydroxyoxime; Lix984N; dynamics; interfacial activity; coalescence