Effect of annealing on two different niobium-clad
stainless steel PEMFC bipolar plate materials
(1. School of Mechanical and Automotive Engineering, University of Ulsan, Ulsan, Korea;
2. Department of Material Science and Engineering, University of Ulsan, Ulsan, Korea;
3. Pacific Northwest National Laboratory, P.O. Box 999, Richland, WA, USA)
2. Department of Material Science and Engineering, University of Ulsan, Ulsan, Korea;
3. Pacific Northwest National Laboratory, P.O. Box 999, Richland, WA, USA)
Abstract: Niobium (Nb)-clad stainless steels(SS) produced via roll bonding are being considered for use in the bipolar plates of polymer electrolyte membrane fuel cell(PEMFC) stacks. Because the roll bonding process induces substantial work hardening in the constituent materials, thermal annealing is used to restore ductility to the clad sheet so that it can be subsequently blanked, stamped and dimpled in forming the final plate component. Two roll bonded materials, niobium clad 340L stainless steel (Nb/340L SS) and niobium clad 434 stainless steel (Nb/434 SS) were annealed under optimized conditions prescribed by the cladding manufacturer. Comparative mechanical testing conducted on each material before and after annealing shows significant improvement in ductility in both cases. However, corresponding microstructural analyses indicate an obvious difference between the two heat treated materials. During annealing, an interlayer with thick less than 1 μm forms between the constituent layers in the Nb/340L SS, whereas no interlayer is found in the annealed Nb/434 SS material. Prior work suggests that internal defects potentially can be generated in such an interlayer during metal forming operations. Thus, Nb/434 SS may be the preferred candidate material for this application.
Key words: clad sheet; bipolar plate; proton exchange membrane fuel cell; annealing