Preparation of primary Al-Si alloy from bauxite tailings by
carbothermal reduction process
carbothermal reduction process
(School of Materials and Metallurgy, Northeastern University, Shenyang 110004, China)
Abstract: Effects of various reaction parameters such as atmospheric pressure, treating temperature, sintering time and bituminite content on the preparation of primary Al-Si alloy by carbothermal reduction of bauxite tailings were investigated by XRD，XRF，infrared absorption carbon-sulfur analysis unit and SEM coupled with EDS. Meanwhile, the mechanism of carbothermal reduction of Al2O3 and SiO2 was discussed. It is found that pressure and temperature are major factors that influence the carbothermal reduction of bauxite tailings. The appropriate conditions for preparation of primary Al-Si alloy are as follows: atmospheric pressure of 0.1 MPa, heating temperature of 1 900 ℃,bituminite content of 95% (mass fraction) of theoretic bituminite content and sintering time of 1 h. Among four mechanisms of carbothermal reduction of Al2O3 and SiO2, the theory of the formation and decomposition of carbides might be the best one to interpret the reaction process.
Key words: primary Al-Si alloy; bauxite tailings; carbothermal reduction process; reduction mechanism