Pressure acid leaching of zinc sulfide concentrate
(Key Laboratory of Ecological Utilization of Multi-metal Intergrown Ores of Ministry of Education,
School of Materials and Metallurgy, Northeastern University, Shenyang 110004, China)
School of Materials and Metallurgy, Northeastern University, Shenyang 110004, China)
Abstract: Effects of particle size of the zinc sulfide concentrate, leaching temperature, solid-to-liquid ratio and additive amount on pressure acid leaching process of the zinc sulfide concentrate were studied. The results indicate that the additive can improve the reaction kinetics and the conversion rate. And sulfur can be successfully separated from the zinc sulfide concentrate as elemental sulfur. The reasonable experiment parameters are obtained as follows: the leaching temperature 150 ℃, oxygen partial pressure 1 MPa, additive amount 1%, solid-to-liquid ratio 1:4, leaching time 2 h, initial sulfuric acid concentration 15%, and particle size less than 44 μm. Under the optimum conditions, the leaching rate of the zinc can reach 95% and the reduction rate of the sulfur can reach 90%.
Key words: zinc sulfide concentrate; pressure acid leaching; zinc; sulfur