Preparation and characterization of ultrafine zinc oxide powder by
hydrothermal method
(1. School of Materials and Metallurgy, Northeastern University, Shenyang 110004, China;
2. Ningbo Institute of Technology, Zhejiang University, Ningbo 315100, China)
2. Ningbo Institute of Technology, Zhejiang University, Ningbo 315100, China)
Abstract: With Zinc acetate and sodium hydroxide as raw materials, while polyethylene glycol employed as dispersant agent, ultrafine zinc oxide powder was synthesized by hydrothermal method. Influence of NaOH concentration on morphology of ZnO powder was studied. The as-synthesized ZnO powder looked like flower cluster and consisted of microrods with hexagonal morphologies. The crystal structure and optical property of the as-prepared powder were also characterized using XRD, UV-visible absorption spectrum and photoluminescence spectrum. The results indicate that ZnO powder is of hexagonal wurtzite structure and well crystallized with high purity. There is a strong excitation absorption peak at 300 nm in UV-visible absorption spectrum and blue shift exists obviously. The optical property of ZnO powder is excellent.
Key words: zinc oxide; hexagonal wurtzite structure; photoluminescence spectrum; optical property