φ−pH diagram of V−Ti−H2O system during pressure acid leaching of
converter slag containing vanadium and titanium
converter slag containing vanadium and titanium
(Key Laboratory of Ecological Utilization of Multi-metal Intergrown Ores of Ministry of Education,
School of Materials and Metallurgy, Northeastern University, Shenyang 110819, China)
School of Materials and Metallurgy, Northeastern University, Shenyang 110819, China)
Abstract: To analyze the thermodynamic characteristics of leaching process of converter slag, φ−pH diagram of V−Ti−H2O system at oxygen partial pressure of 0.5 MPa, ionic mass concentration of 0.1 mol/kg and temperatures ranging from 60 to 200 °C was obtained by recently published critically assessed standard Gibbs energies and activity coefficients of various species. When pH<2, stable regions of V3+, VO2+ and VO2+ exist in the stable region of TiO2. The pH values of stable regions of vanadium and titanium decrease and redox potentials become more positive with the temperature increasing. Vanadium and titanium could be separated by one-step leaching based on thermodynamics. The experiment results of pressure acid leaching of converter slag show that leaching rates of vanadium and titanium are 96.87% and 8.76% respectively, at 140 °C of temperature, 0.5 MPa of oxygen partial pressure, 0.055−0.075mm of particle size, 15:1 of liquid to solid ratio, 120 min of leaching time, 500 r/min of stirring speed and 200 g/L of initial acid concentration. Vanadium and titanium could be selectively separated in the pressure acid leaching process, and the experiment result is in agreement with thermodynamic calculation result.
Key words: φ−pH diagram; V−Ti−H2O system; pressure acid leaching; converter slag; vanadium; titanium