ISSN: 1003-6326
CN: 43-1239/TG
CODEN: TNMCEW

Vol. 21    No. 10    October 2011

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Preparation and photocatalytic activity of BiOCl catalyst
SHI Zhu-qing1, WANG Yan1, 2, FAN Cai-mei1, WANG Yun-fang1, DING Guang-yue1
(1. College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China;
2. College of Chemistry and Bioengineering, Taiyuan University of Science and Technology, Taiyuan 030021, China
)
Abstract: The BiOCl powders prepared by the hydrolysis method were investigated with the X-ray diffractometry (XRD), scanning electron microscopy (SEM) and differential thermal analysis (TG−DTA). The results show that the powders are of the tetragonal primitive crystal structure, composed of homogeneous particles of fine ferrite plates, and stable in the temperature range of 40−600 °C. In addition, the photocatalytic activity of BiOCl powders was evaluated by methyl orange (MO) in aqueous solution illuminated by xenon-lamp, and the effect of the BiOCl amount on the photocatalytic activity was investigated. Moreover, the photocatalytic properties of BiOCl and TiO2-P25 were also compared. The results show that the favorite amount of BiOCl powders is 1.0 g/L for the MO degradation,and the photocatalytic activity of the BiOCl catalyst is comparable to the TiO2-P25 catalyst under the same experiment condition.
Key words: BiOCl; photocatalysis; xenon lamp; methyl orange (MO)
Superintended by The China Association for Science and Technology (CAST)
Sponsored by The Nonferrous Metals Society of China (NFSOC)
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