Electrodeposition conditions of metallic nickel in electrolytic membrane reactor
(1. School of Marine Science and Technology, Harbin Institute of Technology at Weihai, Weihai 264209, China;
2. Henan Jindan Lactic Acid Technology Co. Ltd., Dancheng 477150, China)
2. Henan Jindan Lactic Acid Technology Co. Ltd., Dancheng 477150, China)
Abstract: The process parameters were optimized for the electrodeposition of nickel in an electrolytic membrane reactor. Nickel(II) and boric acid concentrations, pH and temperature were varied to evaluate the changes in current efficiency and specific energy consumption of nickel electrodeposition. The catholyte was aqueous nickel(II) sulfate and boric acid, and the anolyte was sulfuric acid solution. An anionic membrane separated the anolyte from the catholyte while maintained a conductive path between the two compartments. The results indicated that the cathode current efficiency increased with the increase of nickel concentration, pH and boric acid concentration, and decreased with the increase of current density and stirring rate. A maximum current efficiency of 97.15% was obtained under the optimized conditions of electrolyte composition of 40 g/L Ni and 40 g/L boric acid at temperature of 42 °C and pH of 6 with a cathode current density of 300 A/m2.
Key words: nickel; electrodeposition; anion-exchange membrane; electrolytic membrane reactor