Synthesis of (Ca, Mg)-α′-Sialon-AlN-BN powders from boron-rich blast furnace slag by microwave carbothermal reduction-nitridation
(1. School of Materials and Metallurgy, Northeastern University, Shenyang 110819, China;
2. Liaoning Key Laboratory for Recycling Science of Metallurgical Resources,
Northeastern University, Shenyang 110819, China;
3. Liaoning Key Laboratory for Ecologically Comprehensive Utilization of Boron Resource and Materials,
Northeastern University, Shenyang 110819, China)
2. Liaoning Key Laboratory for Recycling Science of Metallurgical Resources,
Northeastern University, Shenyang 110819, China;
3. Liaoning Key Laboratory for Ecologically Comprehensive Utilization of Boron Resource and Materials,
Northeastern University, Shenyang 110819, China)
Abstract: (Ca, Mg)-α′-Sialon-AlN-BN powders were synthesized by the carbothermal reduction and nitridation (CRN) method using boron-rich slag, one of the intermediate products from pyrometallurgy separation of pageit, as the staring material. The influences of synthesis temperature and holding time on the phase composition and microstructure during the microwave CRN were studied by XRD, SEM and EDS. The comparison between two heating techniques, conventional and microwave heating, on the synthesized powder was presented as well. The experimental results revealed that the phase compositions and microstructures of the synthesized products were greatly affected by the synthesis temperature and holding time. With an increase in the synthesis temperature or holding time, the relative amount of α′-Sialon increased and α′-Sialon became the main crystalline phase at 1400 °C for 6 h. The synthesized products also contained AlN, BN and a small amount of β-SiC. Elongated α′-Sialon grains, short rod AlN grains, aggregate nanoscale BN grains were observed in the synthesized powders. The reaction temperature of microwave heating method was reduced by 80 °C, the reaction time was shortened by 2 h, and more elongated α′-Sialon grains with large aspect ratio were observed.
Key words: boron-rich blast furnace slag; carbothermal reduction-nitridation; microwave; (Ca, Mg)-α′-Sialon-AlN-BN; powders