Influence of heat treatment on electrochemical properties of Ti1.4V0.6Ni alloy electrode containing icosahedral quasicrystalline phase
(1. School of Materials Science and Engineering, Changchun University of Science and Technology,
Changchun 130022, China;
2. State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry,
CAS, Changchun 130022, China)
Changchun 130022, China;
2. State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry,
CAS, Changchun 130022, China)
Abstract: The structures and electrochemical properties of the Ti1.4V0.6Ni ribbon before and after heat treatment are investigated systematically. The structure of the sample is characterized by X-ray powder diffraction analysis. Electrochemical properties including the discharge capacity, the cyclic stability and the high-rate discharge ability are tested. X-ray powder diffraction analysis shows that after heat treatment at 590 °C for 30 min, all samples mainly consist of the icosahedral quasicrystal phase (I-phase), Ti2Ni phase (FCC), V-based solid solution phase (BCC) and C14 Laves phase (hexagonal). Electrochemical measurements show that the maximum discharge capacity of the alloy electrode after heat treatment is 330.9 mA·h/g under the conditions that the discharge current density is 30 mA/g and the temperature is 30 °C. The result indicates that the cyclic stability and the high-rate discharge ability are all improved. In addition, the electrochemical kinetics of the alloy electrode is also studied by electrochemical impedance spectroscopy (EIS) and hydrogen diffusion coefficient (D).
Key words: quasicrystal; Ti1.4V0.6Ni alloy; electrochemical properties; cyclic stability; high-rate discharge; discharge capacity