Electroplating zinc transition layer for electroless nickel plating on AM60 magnesium alloys
(1.College of Chemistry and Life Science, Shenyang Normal University, Shenyang 110034, China
2.辽宁省沈阳市科学院金属研究所
3.北京市北京化工大学材料科学与工程学院
4.Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China)
2.辽宁省沈阳市科学院金属研究所
3.北京市北京化工大学材料科学与工程学院
4.Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China)
Abstract: Electroplating zinc coating as transition layer of electroless nickel plating on AM60 magnesium alloys was investigated. The zinc film can be deposited in a pyrophosphate bath at 50-60 ℃ under current density of 0.5-1.5 A/dm2. A new fore treatment technology was applied by acid cleaning with a solution containing molybdate and phosphorous acid, by alkaline cleaning in a bath containing molybdate and sodium hydroxide. The subsequent electroless plating was carried out in nickel sulfate bath. The SEM observation shows that the deposition is uniform and compact. The polarization curve measurements show that the corrosion potential of the zinc plating in 3.5% NaCl is about -1.3 V(vs SCE) which is noble than that of magnesium substrate. The zinc electroplating can be applied as the pretreatment process for electroless nickel plating on magnesium alloys.
Key words: magnesium alloy; AM60; electroplating zinc; electroless nickel plating; corrosion resistance