Desilication from titanium–vanadium slag by alkaline leaching
(1. National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology,
Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
2. Key Laboratory of Green Process and Engineering, Institute of Process Engineering,
Chinese Academy of Sciences, Beijing 100190, China)
Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
2. Key Laboratory of Green Process and Engineering, Institute of Process Engineering,
Chinese Academy of Sciences, Beijing 100190, China)
Abstract: A hydrometallurgical process for the selective removal of silicon from titanium–vanadium slag by alkaline leaching was investigated. X-ray diffraction, scanning electron microscopy and electron dispersive spectroscopy were used to characterize the samples. The results show that anosovite, pyroxene and metallic iron are the major components of the titanium–vanadium slag. Anosovite is presented in granular and plate shapes, and pyroxene is distributed in the anosovite crystals. Metallic iron is spheroidal and wrapped in anosovite. Silicon is mainly in the pyroxene, and titanium and vanadium are mainly in the anosovite. The effects of agitation speed, leaching temperature, leaching time, sodium hydroxide concentration and liquid–solid (L/S) mass ratio on the leaching behavior of silica from titanium–vanadium slag were investigated. The leaching temperature and L/S mass ratio played considerable role in the desilication process. Under the optimal conditions, 88.2% silicon, 66.3% aluminum, 27.3% manganese, and only 1.2% vanadium were leached out. The desilication kinetics of the titanium–vanadium slag was described by the chemical control model. The apparent activation energy of the desilication process was found to be 46.3 kJ/mol.
Key words: desilication; titanium–vanadium slag; alkaline leaching; kinetics