Kinetics of extracting magnesium from mixture of calcined magnesite and calcined dolomite by vacuum aluminothermic reduction
(School of Materials and Metallurgy, Northeastern University, Shenyang 110819, China)
Abstract: The vacuum aluminothermic reduction of the mixture of calcined magnesite and calcined dolomite was studied. An isothermal reduction method satisfying the vacuum aluminothermic reduction was proposed. The experiments were carried out at 4 Pa. The results indicate that the reduction rate is increased with increasing temperature, content of aluminum and pellet forming pressure. The XRD patterns of pellets at different reduction stages confirm that the reduction process can be roughly classified into three stages: the formation of MgAl2O4, and Ca12Al14O33 phases; the phase transformation from MgAl2O4 and C12A7 to CaAl2O4; the formation of CaAl4O7 phase. The experimental data were divided into three parts according to the kinetic models. The apparent activation energies of the three parts were determined to be 98.2, 133.0 and 223.3 kJ/mol, respectively.
Key words: magnesium; kinetics; aluminothermic reduction; magnesite; dolomite