Reaction kinetics of roasting high-titanium slag with concentrated sulfuric acid
(1. School of Materials and Metallurgy, Northeastern University, Shenyang 110819, China;
2. Department of Chemistry, Shenyang Medical College, Shenyang 110034, China)
2. Department of Chemistry, Shenyang Medical College, Shenyang 110034, China)
Abstract: A novel method of roasting high-titanium slag with concentrated sulfuric acid was proposed to prepare titanium dioxide, and the roasting kinetics of titania was studied on the basis of roasting process. The effects of roasting temperature, particle size, and acid-to-ore mass ratio on the rate of roasting reaction were investigated. The results showed that the roasting reaction is fitted to a shrinking core model. The results of the kinetic experiment and SEM and EDAX analyses proved that the reaction rate of roasting high-titanium slag with concentrated sulfuric acid is controlled by the internal diffusion on the solid product layer. According to the Arrhenius expression, the apparent activation energy of the roasting reaction is 18.94 kJ/mol.
Key words: roasting kinetics; high-titanium slag; concentrated sulfuric acid; titania