Effect of copper, sulfur, arsenic and antimony on silver distribution in phases of lead blast furnace
(1. Metallurgy and Materials Department, IPN-ESIQIE, UPALM, Zacatenco, C.P. 07738, Mexico D.F., Mexico;
2. Academic Area of Earth Science and Materials, UAEH, Col. Carboneras,
Mineral de la Reforma, C.P. 42184, Hidalgo, México;
3. Servicios Administrativos Pe？oles S.A de C.V. Prol. Comonfort Sur 2050,
Col. L. Echeverria, Torreon, C.P. 27300 Coahuila, Mexico)
2. Academic Area of Earth Science and Materials, UAEH, Col. Carboneras,
Mineral de la Reforma, C.P. 42184, Hidalgo, México;
3. Servicios Administrativos Pe？oles S.A de C.V. Prol. Comonfort Sur 2050,
Col. L. Echeverria, Torreon, C.P. 27300 Coahuila, Mexico)
Abstract: An experimental study was carried out to estimate the effect of the lead impurities on the silver distribution in the phases formed in the lead blast furnace. Samples of sinter with different contents of Cu, S, As and Sb were equilibrated under reducing atmosphere (p(CO)/p(CO2)=2.45) at 1573 K in a tube furnace and slowly cooled. The samples were characterized by scanning electron microscopy and microanalysis (SEM-EDS). There were five immiscible phases: slag (CaO, FeO and SiO2), matte (S, Cu and Fe), speiss (As, Fe and Cu), Cu-Sb phase and lead bullion (Pb, Ag, Sb, Cu, etc). The results showed that Cu and Sb promote silver losses during the process since they form a liquid solution with higher silver solubility than liquid bullion. Sulfur and arsenic react with copper to form the matte and speiss phases, respectively. The effect of S and As is to reduce the amount of Cu-Sb alloy and then the silver losses from the bullion.
Key words: lead blast furnace; silver; lead impurities