Effect of Schiff base as corrosion inhibitor on AZ31 magnesium alloy in hydrochloric acid solution
(1. Department of Chemistry, Sri Ramanujar Engineering College, Chennai 600048, India;
2. Department of Chemistry, BS Abdur Rahman University, Chennai 600048, India)
2. Department of Chemistry, BS Abdur Rahman University, Chennai 600048, India)
Abstract: Schiff base derived from the condensation reaction of analar grade 1-amino-2-naphthol 4-sulphonic acid with cinnamaldehyde was prepared under microwave condition. The Schiff base was analysed by infrared spectroscopy. This Schiff base as a corrosion inhibitor of AZ31 magnesium alloy in 0.05 mol/L HCl solution was studied. The inhibition effect of the Schiff base compound (4Z)-4-(3-phenyl allylidene amino)-3-hydroxy naphthalene-1-sulfonic acid (AC) on AZ31 magnesium alloy corrosion was studied using mass loss, potentiodynamic polarization technique, electrochemical impedance spectroscopy methods. The potentiodynamic polarization curve shows that Schiff base AC inhibits both anodic and cathodic reactions at all concentration, which indicates it is a mixed type inhibitor. EIS results indicate that as the additive concentration is increased, the polarization resistance increases whereas double-layer capacitance decreases. The adsorption of AC on the AZ31 magnesium alloy surface in 0.05 mol/L HCl obeys the Langmuir adsorption isotherm.
Key words: Schiff base; AZ31 magnesium alloy; corrosion inhibitor; potentiodynamic polarization; electrochemical impedance spectroscopy