Discharge behavior and electrochemical properties of Mg-Al-Sn alloy anode for seawater activated battery
(School of Materials Science and Engineering, Central South University, Changsha 410083, China)
Abstract: Mg-Al-Sn alloy is one of the new developed anode materials for seawater activated batteries. The potentiodynamic polarization, galvanostatic discharge and electrochemical impedance spectroscopy of Mg-6%Al-1%Sn and Mg-6%Al-5%Sn (mass fraction) alloys in seawater were studied and compared with the commercial AZ31 and AP65 alloys. The results show that the Mg-6%Al-1%Sn alloy obtains the most negative discharge potential of average -1.611 V with a electric current density of 100 mA/cm2. EIS studies reveal that the Mg-Al-Sn alloy/seawater interfacial electrochemical process is determined by an activation controlled reaction. The assembled prototype batteries with Mg-6%Al-1%Sn alloy as anodes and AgCl as cathodes exhibit a satisfactory integrated discharge properties.
Key words: magnesium anode material; galvanostatic discharge; anodic dissolution; seawater activated batteries