Secondary reaction mechanism of leaching process of calcium aluminate slag
(1. School of Materials Science and Engineering, Hebei University of Science and Technology,
Shijiazhuang 050018, China;
2. Hebei Key Laboratory of Material Near-net Forming Technology,
Hebei University of Science and Technology, Shijiazhuang 050018, China)
Shijiazhuang 050018, China;
2. Hebei Key Laboratory of Material Near-net Forming Technology,
Hebei University of Science and Technology, Shijiazhuang 050018, China)
Abstract: SiO2 in calcium aluminate slag exists in the form of γ-2CaO·SiO2 which is more stable than β-2CaO·SiO2. However, it is decomposed by sodium carbonate solution during leaching process, leading to the secondary reaction. The extent of secondary reaction and reaction mechanism of calcium aluminate slag were studied using XRD. The results show that the decomposition rate of γ-2CaO·SiO2 increases with the increase in leaching time and sodium carbonate concentration. The main products of secondary reaction are the mixture of hydrogarnet and sodium hydrate alumina-silicate. SiO2 concentration rises firstly and then drops with the increase of leaching temperature. XRD results indicate that the stable product of secondary reaction at low temperature is hydrogarnet. But hydrogarnet is transformed into sodium hydrate alumina-silicate at high temperature.
Key words: calcium aluminate slag; secondary reaction; alumina; leaching