Isothermal thermo-analytical study and decomposition kinetics of non-activated and mechanically activated indium tin oxide (ITO) scrap powders treated by alkaline solution
(Department for Dynamics and Matter Structure, Faculty of Physical Chemistry,
University of Belgrade, Belgrade 11001, Serbia)
University of Belgrade, Belgrade 11001, Serbia)
Abstract: Isothermal decomposition process of chemically transforming indium tin oxide (ITO) powders into indium (III) hydroxide powders was investigated. Two types of powders were analyzed, i.e., non-activated and mechanically activated. It has been found that in the case of activated sample, shorter induction periods appear, which permits growth of smaller crystals, while in the case of non-activated sample, long induction periods appear, characterized by the growth of larger crystals. DAEM approach has shown that decomposition processes of non-activated and mechanically activated samples can be described by contracting volume model with a linear combination of two different density distribution functions of apparent activation energies (Ea), and with first-order model, with a single symmetrical density distribution function of Ea, respectively. It was established that specific characteristics of particles not only affect the mechanism of decomposition processes, but also have the significant impact on thermodynamic properties.
Key words: indium tin oxide; mechanical activation; chemical preparation; grain boundaries; thermal properties; decomposition kinetics