Electrodeposition of iridium from composite ionic liquid
(Key Laboratory of Bio-inspired Smart Interfacial Science and Technology of Ministry of Education,
School of Chemistry and Environment, Beihang University, Beijing 100191, China)
School of Chemistry and Environment, Beihang University, Beijing 100191, China)
Abstract: In order to study the electrodeposition process of iridium in composite ionic liquid, the effects of N, N-dimethylacetamide (DMAC) on the viscosity, conductivity and electrochemical stability of composite ionic liquid BMIC-BMIBF4, as well as the electrochemical behavior of IrCl3 in this system were studied. Iridium (Ir) coatings were deposited at different constant potentials and characterized by SEM and XRD. The results show that the addition of DMAC can evidently decrease the viscosity of the composite system, increase conductivity and improve electrochemical stability of the composite system. Cyclic voltammograms of a Au electrode illustrate that the process controlled by diffusion rate is irreversible with the average charge transfer coefficient of 0.170 and average diffusion coefficient of 1.096×10-6 cm2/s. In addition, SEM image shows that Ir film deposited at the reduction peak potential is dense and even, while XRD pattern shows that Ir deposit is polycrystalline structure.
Key words: composite ionic liquid; iridium; N, N-dimethylacetamide; electrodeposition