Corrosion properties of stainless steel 316L/Ni-Cu-P coatings in warm acidic solution
(1. Jiangsu Key Laboratory of Advanced Structural Materials and Application Technology, Nanjing 211167, China;
2. School of Materials Engineering, Nanjing Institute of Technology, Nanjing 211167, China)
2. School of Materials Engineering, Nanjing Institute of Technology, Nanjing 211167, China)
Abstract: In order to improve corrosion resistance of stainless steel 316L in warm acidic solution, Ni-Cu-P coatings with high copper and phosphorus contents were deposited onto stainless steel 316L substrates via electroless plating. The structure of the film and its resistance to corrosion in a warm acidic environment were investigated using scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), X-ray diffraction spectrometry (XRD), polarization curves, electrochemical impedance spectroscopy (EIS), and dipping corrosion tests, respectively. The results demonstrate that Ni-Cu-P coatings consist of two types of nodules, which are 19.98% Cu and 39.17% Cu (mass fraction) respectively. The corrosion resistance of the 316L substrate when subjected to a warm acidic solution is significantly improved by the addition of the new type of the Ni-Cu-P coating. The as-plated coatings demonstrate better corrosion resistance than annealed coatings. As-plated coatings and those annealed at 673 K are found to corrode selectively, while pitting is observed to be the main corrosion mechanism of coatings annealed at 773 and 873 K.
Key words: Ni-Cu-P coating; stainless steel 316L; corrosion resistance; corrosion mechanism; warm acidic solution