Fabrication, tribological and corrosion behaviors of detonation gun sprayed Fe-based metallic glass coating
(1. State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China;
2. State Key Laboratory of Construction Machinery,
Zoomlion Heavy Industry Science and Technology Co., Ltd., Changsha 410013, China)
2. State Key Laboratory of Construction Machinery,
Zoomlion Heavy Industry Science and Technology Co., Ltd., Changsha 410013, China)
Abstract: A metallic glass coating with the composition of Fe51.33Cr14.9Mo25.67Y3.4C3.44B1.26 (mole fraction, %) on the Q235 stainless steel was developed by the detonation gun (D-gun) spraying process. The microstructure and the phase aggregate were analyzed by scanning electron microscopy and X-ray diffractometry, respectively. Microhardness, wear resistance and corrosion behavior were assessed using a Vickers microhardness tester, a ball-on-disk wear testing machine and the electrochemical measurement method, respectively. Microstructural studies show that the coatings possess a densely layered structure with the porosity less than 2.1%. The tribological behavior of the coatings examined under dry conditions shows that their relative wear resistance is five times higher than that of the substrate material. Both adhesive wear and abrasive wear contribute to the friction, but the former is the dominant wear mechanism of the metallic glass coatings. The coatings exhibit low passive current density and extremely wide passive region in 3.5% NaCl solution, thus indicating excellent corrosion resistance.
Key words: Fe-based metallic glass coating; detonation gun spraying; microstructure; tribological behavior; corrosion behavior