Temperature-programmed pyrolysis of magnesium ammonium phosphate and removal of ammonia-nitrogen by its pyrolysate
(1. Shenzhen Key Laboratory of Industrial Water Conservation & Municipal Wastewater Resources Technology, Shenzhen Polytechnic, Shenzhen 518055, China;
2. School of Civil Engineering, Guangzhou University, Guangzhou 510006, China)
2. School of Civil Engineering, Guangzhou University, Guangzhou 510006, China)
Abstract: In order to achieve the dual goals of complete deamination of magnesium ammonium phosphate (MAP) and ensure the pyrolysate’s good removal properties towards ammonia-nitrogen, a temperature-programmed method for the pyrolysis of MAP was studied, as well as the thermodynamic and kinetic processes involved in the removal reaction system between MAP pyrolysate and aqueous ammonium. It was found that the pyrolysis method and pyrolysis final temperature had significant effects on the MAP pyrolysate’s removal properties towards aqueous ammonium, and the following conditions were deemed to be more appropriate: pyrolysis final temperature and heating rate at 180 °C and 5 °C/min, respectively, and a pH level of 9.5 for the removal reaction system. The resultant ammonium removal capacity by the MAP pyrolysate was 95.62 mg/g. After 120 min, the removal rate with an initial concentration of 1000 mg/L was 82%. The kinetic and thermodynamic results indicated that the removal of aqueous ammonium by MAP pyrolysate was the exchange process between H+ and NH4+ via MAP precipitation. The kinetics complied with the Lagergren quasi second-order model with an equilibrium time of 120 min, while the isothermal curves complied with the Freundlich model.
Key words: magnesium ammonium phosphate; temperature-programmed heating; pyrolysate; ammonia-nitrogen