Leaching of iron concentrate separated from kiln slag in zinc hydrometallurgy with hydrochloric acid and its mechanism
(1. School of Metallurgy and Environment, Central South University, Changsha 410083, China;
2. Institute of Metallurgy, China Nerin Engineering Co., Ltd., Nanchang 330031, China)
2. Institute of Metallurgy, China Nerin Engineering Co., Ltd., Nanchang 330031, China)
Abstract: It is taken as a novel prospective process to treat iron concentrate from hydrometallurgical zinc kiln slag for comprehensive utilization of valuable metals by a hydrochloric acid leaching-spray pyrolysis method. The leaching mechanism of different valuable metals was studied. The results revealed that the leaching rates of Ag, Pb, Cu, Fe, As and Zn were 99.91%, 99.25%, 95.12%, 90.15%, 87.58% and 58.15%, respectively with 6 mol/L HCl and L/S ratio of 10:1 at 60 °C for 120 min. The action of SiO2 in leaching solution was also studied. The results showed that the precipitation and settlement of SiO2(amorphous) adsorbed part of metal ions in solution, which greatly inhibited the leaching of Cu, Fe, As and Zn, so it is crucial to control the precipitation of amorphous SiO2.
Key words: kiln slag; iron concentrate; hydrochloric acid leaching; amorphous silica