Mineralogical characterization and pretreatment for antimony extraction by ozone of antimony-bearing refractory gold concentrates
(1. School of Metallurgy and Environment, Central South University, Changsha 410083, China;
2. Cleaner Metallurgical Engineering Research Center,
China Nonferrous Metals Industry Association, Changsha 410083, China)
Abstract: The mineralogical characterization of antimony-bearing refractory gold concentrates and the antimony extraction by ozone in HCl solution were investigated. The mineralogical study shows that there exist stibnite(Sb2S3), arsenopyrite(FeAsS), pyrite(FeS2) and quartz in the concentrates, and the gold is mainly (67.42%) encapsulated in sulfides. The antimony extraction by ozone in hydrochloric acid was employed and the influences of temperature, liquid/solid ratio, HCl concentration and stirring speed on the extraction of antimony were investigated. High antimony extraction (93.75%) is achieved under the optimized conditions. After the pretreatment by ozone, the antimony is recovered efficiently and the gold is enriched in the leaching residue.
Key words: antimony-bearing refractory gold concentrates; ozone; pretreatment; mineralogical characterization; antimony extraction