Shape memory TiNi powders produced by plasma rotating electrode process for additive manufacturing
(1. State Key Laboratory of Porous Metal Materials, Northwest Institute for Non-ferrous Metal Research, Xi’an 710016, China;
2. State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China;
3. School of Materials Science and Engineering, Northeastern University, Shenyang 110819, China;
4. Xi’an Sailong Metal Materials Co., Ltd., Xi’an 710016, China;
5. Department of Chemical and Materials Engineering, The University of Auckland, Private Bag 92019, Auckland 1142, New Zealand)
Abstract: This study aimed to produce spherical TiNi powders suitable for additive manufacturing by plasma rotating electrode process (PREP). Scanning electron microscopy, X-ray diffractometry and differential scanning calorimetry were used to investigate the surface and inner micro-morphology, phase constituent and martensitic transformation temperature of the surface and inner of the atomized TiNi powders with different particle sizes. The results show that the powder surface becomes smoother and the grain becomes finer gradually with decreasing particle size. All the powders exhibit a main B2-TiNi phase, while large powders with the particle size ≥178 μm contain additional minor Ti2Ni and Ni3Ti secondary phases. These secondary phases are a result of the eutectoid decomposition during cooling. Particles with different particle sizes have experienced different cooling rates during atomization. Various cooling rates cause different martensitic transformation temperatures and routes of the TiNi powders; in particular, the transformation temperature decreases with decreasing particle size.
Key words: atomization; plasma rotating electrode process; TiNi; particle size; martensitic transformation