Effect of Zn addition on microstructure and mechanical properties of cast Mg-Gd-Y-Zr alloys
(1. College of Materials Science and Engineering, North University of China, Taiyuan 030051, China;
2. College of Mechatronic Engineering, North University of China, Taiyuan 030051, China;
3. School of Mechanical, Materials and Mechatronic Engineering, University of Wollongong, Wollongong, NSW 2522, Australia)
2. College of Mechatronic Engineering, North University of China, Taiyuan 030051, China;
3. School of Mechanical, Materials and Mechatronic Engineering, University of Wollongong, Wollongong, NSW 2522, Australia)
Abstract: The effects of Zn addition on the microstructure and mechanical properties of Mg-10Gd-3Y-0.6Zr (wt.%) alloys in the as-cast, solution-treated, and peak-aged conditions were investigated. Experimental results reveal that the microstructure of the as-cast alloy without Zn consists of α-Mg and Mg24(Gd,Y)5 phases, and the alloy with 0.5 wt.% Zn consists of α-Mg, (Mg,Zn)3(Gd,Y) and Mg24(Gd,Y,Zn)5 phases. With the addition of Zn increasing to 1 wt.%, the Mg24(Gd,Y,Zn)5 phase disappears and some needle-like stacking faults distribute along the grain boundaries. Moreover, the 18R long-period stacking ordered (LPSO) phase is observed in the as-cast alloy with 2 wt.% Zn. After solution treatment, the Mg24(Gd,Y)5 and Mg24(Gd,Y,Zn)5 eutectic phases are completely dissolved, and the (Mg,Zn)3(Gd,Y) phase, needle-like stacking faults and 18R LPSO phase all transform into 14H LPSO phase. Both the suitable volume fraction of 14H LPSO phases and the fine ellipsoidal-shaped β′ phases make the peak-aged alloy with 0.5 wt.% Zn exhibit excellent comprehensive mechanical properties and the UTS, YS and elongation are 338 MPa, 201 MPa and 6.8%, respectively.
Key words: Mg alloy; heat treatment; microstructure; mechanical property; LPSO phase