In-situ hydrothermal synthesis of Ni-MoO2 heterostructure on porous bulk NiMo alloy for efficient hydrogen evolution reaction
(1. School of Materials Science and Engineering, Nanchang Hangkong University, Nanchang 330063, China;
2. School of Business, Macau University of Science and Technology, Macau 999078, China)
2. School of Business, Macau University of Science and Technology, Macau 999078, China)
Abstract: The Ni-MoO2 heterostructure was synthesized in suit on porous bulk NiMo alloy by a facile powder metallurgy and hydrothermal method. The results of field emission scanning electron microscopy (SEM), field emission transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS) reveal that the as-prepared electrode possesses the heterostructure and a layer of Ni(OH)2 nanosheets is formed on the surface of Ni-MoO2 electrode simultaneously after hydrothermal treatment, which provides abundant interface and much active sites, as well as much active specific surface area. The results of hydrogen evolution reaction indicate that the Ni-MoO2 heterostructure electrode exhibits excellent catalytic performance, requiring only 41 mV overpotential to reach the current density of 10 mA/cm2. It also possesses a small Tafel slope of 52.7 mV/dec and long-term stability of electrolysis in alkaline medium.
Key words: hydrogen evolution reaction; Ni-MoO2 heterostructure; powder metallurgy; porous bulk electrocatalyst; NiMo alloy