Effect of additives on growth of ferronickel grains and metal–slag separation behavior
(1. College of Materials Science and Engineering, Chongqing University, Chongqing 400044, China;
2. Chongqing Key Laboratory of Vanadium–Titanium Metallurgy and Advanced Materials, Chongqing University, Chongqing 400044, China)
2. Chongqing Key Laboratory of Vanadium–Titanium Metallurgy and Advanced Materials, Chongqing University, Chongqing 400044, China)
Abstract: Na2S, Na2CO3, FeO, FeS and carbon were used to regulate the properties of slag or metal fractions, and their effects on metal growth and metal–slag separation behavior were investigated. The growth of ferronickel grains can be enhanced by adding these additives, and Na2S was the most effective. Na2S, Na2CO3 and FeO mainly affected the properties of slag, while carbon and FeS affected the metal fraction. The onset temperature of metal–slag separation was 1297 °C for the sample without additive, which was decreased to 1123 and 1101 °C after adding 3.30 wt.% Na2S and 4.47 wt.% Na2CO3, respectively. The onset temperature of metal–slag separation was mainly controlled by the slag fraction. The average apparent activation energy of metal grain growth was 125.32 kJ/mol without additive, and it decreased obviously after adding different additives. Na2S also had the most remarkable effect on the decrease in activation energy.
Key words: nickel laterite ore; slag properties; metal growth; metal–slag separation; kinetics