New compound N-methyl-N-isopropyl octanthioamide for palladium selective extraction and separation from HCl media

Jun-lianWANG,LuLIU,Guo-dongXU,Pei-longWANG,Guo-yongHUANG,Feng-shanYU,

doi:10.1016/S1003-6326(23)66207-7

Transactions of Nonferrous Metals Society of China >

2023 , Vol. 33 >Issue 5: 1609 - 1618

DOI: https://doi.org/10.1016/S1003-6326(23)66207-7

Mining, Minerals Processing and Metallurgical Engineering

New compound N-methyl-N-isopropyl octanthioamide for palladium selective extraction and separation from HCl media

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Jun-lian WANG^1,2,³, Lu LIU¹, Guo-dong XU¹, Pei-long WANG¹, Guo-yong HUANG⁴, Feng-shan YU^3,4

1. School of Civil and Resource Engineering, University of Science and Technology Beijing, Beijing 100083, China;
2. Key Laboratory for High Efficient Mining and Safety of Metal Mines, Ministry of Education, University of Science and Technology Beijing, Beijing 100083, China;
3. Jiangxi Province Han’s Precious Metals Co., Ltd., Shangrao 335500, China;
4.State Key Laboratory of Heavy Oil Processing, College of Chemical Engineering, China University of Petroleum-Beijing, Beijing 102249, China

Online published: 2023-05-25

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Abstract

To seek more efficient extractant for Pd recovery from leaching solution of spent automotive catalysts, a new compound N-methyl-N-isopropyl octanthioamide (TA-813) was synthesized and characterized through FT-IR, ¹H NMR, ESI-MS and elemental analysis. Its extraction and stripping behaviors for Pd were studied. To evaluate its reusability performance, extraction-stripping cycles were carried out. Finally, TA-813 was applied to separating Pd from simulated leaching solution of spent automotive catalysts. TA-813 shows fast extraction kinetics, high extraction efficiency and specific selectivity for Pd. During extraction two TA-813 molecules coordinate with one Pd. The loaded Pd in the organic phase is efficiently stripped by neutral and acidic thiourea solutions. TA-813 shows no loss in activity after eight extraction-stripping cycles. Even from simulated leaching solution of spent automotive catalysts, in which the concentrations of some purities (La, Ce, Mg, Al) are much higher than that of Pd, Pd is still selectively extracted.

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Jun-lianWANG,LuLIU,Guo-dongXU,Pei-longWANG,Guo-yongHUANG,Feng-shanYU, . New compound N-methyl-N-isopropyl octanthioamide for palladium selective extraction and separation from HCl media[J]. Transactions of Nonferrous Metals Society of China, 2023 , 33(5) : 1609 -1618 . DOI: 10.1016/S1003-6326(23)66207-7

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