Batch experiments were conducted to remove fluoride from simulated flue-gas scrubbing wastewater using La(NO₃)₃·6H₂O. The effects of SO₄^2- concentration and addition sequence on residual fluoride concentration and precipitates properties (mass, morphology, phase structure and composition) were investigated using fluorine ion-selective electrode, SEM, EDS and XRD. The results show that precipitates obtained in the presence of SO₄^2- mainly consisted of LaF₃ in irregular bulk shape with high crystallinity. However, amorphous particles were observed in the precipitates, which were speculated to be La[SO₄]F. Due to the smaller stoichiometric coefficient of F/La in La[SO₄]F compared to that in LaF₃, the residual fluoride concentration increased as the SO₄^2- concentration ascended. Subsequent addition of SO₄^2- after lanthanum salt could inhibit the formation of amorphous particles, and further reduce the residual fluoride concentration. At a La/F molar ratio of 1:3.0, the subsequent addition of SO₄^2- (0.02 mol/L) after La(NO₃)₃？6H₂O could obtain a residual fluoride concentration of 6.9 mg/L, lower than the required fluoride emission level. Further increasing the La/F molar ratio could reduce residual fluoride concentration to below 2 mg/L, while the risk of retaining La³⁺ would emerge.