Materials Science and Engineering

Effect of Cr coating on creep behavior of zircaloy-4 alloy

  • 左 鼎,杜沛南,罗 威,陈 寰,王 昱,韦天国,张瑞谦,刘会群
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  • 1. School of Materials Science and Engineering, Central South University, Changsha 410083, China;
    2. Science and Technology on Reactor Fuel and Materials Laboratory, Nuclear Power Institute of China, Chengdu 610213, China;
    3. State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China

Online published: 2025-11-04

Abstract

The effects of Cr coating, deposited by chemical vapor deposition, on the creep properties of Zr-4 alloy and the results for its stability during long-time service were reported. Its microstructure was studied by scanning electron microscopy, electron probe microanalysis, and electron backscatter diffraction. Results show that the grains of the Zr-4 matrix were equiaxed, exhibiting á0001? texture parallel to the normal direction (á0001?//ND). Moreover, after the creep test, coated samples displayed a lower number of subgrain boundaries within their matrix compared with uncoated samples. Thus, the application of a Cr coating is instrumental in minimizing the stress on Zr-4, ultimately contributing to an enhancement in creep resistance of the coated samples. The Cr coating exhibits a high stability during long-term diffusion test. The coating cracks at a minimum stress of 157 MPa at 350 °C and 137 MPa at 400 °C. The Monkman-Grant relationship between the steady-state creep rate and creep fracture time was derived using a systematic summary of data pertaining to creep fracture.

Cite this article

左 鼎,杜沛南,罗 威,陈 寰,王 昱,韦天国,张瑞谦,刘会群 . Effect of Cr coating on creep behavior of zircaloy-4 alloy[J]. Transactions of Nonferrous Metals Society of China, 2024 , 34(5) : 1533 -1546 . DOI: 10.1016/S1003-6326(24)66489-7

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