The solid-state reaction behavior of MgO-V₂O₅ mixtures with different molar ratios was explored. The solubility of the solid-state reaction products (magnesium vanadates) in water at 25-55 °C was measured using the isothermal solution saturation method. The dissolution behavior and kinetics of the magnesium vanadates in dilute sulfuric acid were also investigated. The results showed that the molar ratio of MgO to V₂O₅ and roasting temperature significantly influenced the phase transformation of the solid-state reaction product. MgV₂O₆ exhibits the highest solubility in water, followed by Mg₂V₂O₇ and Mg₃V₂O₈. The dissolution rate of magnesium vanadates in dilute sulfuric was significantly increased with the decrease of pH from 4.0 to 2.5 and the temperature increase from 30 to 70 °C. The dissolution of magnesium vanadate can be described using a second-order pseudo-homogeneous reaction model.