MATERIALS SCIENCE AND ENGINEERING

Synergistic enhancement of strength and plasticity in CoCrFeNiMn high-entropy alloys by novel core−shell microstructure design

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  • 1. Key Laboratory of Advanced Technologies of Materials, Ministry of Education, Southwest Jiaotong University, Chengdu 610031, China;
    2. School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu 610031, China;
    3. School of Engineering and Materials Science, Queen Mary University of London, London E1 4NS, United Kingdom;
    4. Institute for Applied Materials (IAM-WK), Karlsruhe Institute of Technology (KIT), Karlsruhe 76131, Germany

Online published: 2025-12-10

Abstract

The novel core−shell SiC@CoCrFeNiMn high-entropy alloy (HEA) matrix composites (SiC@HEA) were successfully prepared via mechanical ball milling and vacuum hot-pressing sintering (VHPS). After sintering, the microstructure was composed of FCC solid solution, Cr23C6 carbide phases, and Mn2SiO4 oxy-silicon phase. The relative density, hardness, tensile strength, and elongation of SiC@HEA composites with 1.0 wt.% SiC were 98.5%,  HV 358.0, 712.3 MPa, and 36.2%, respectively. The core−shell structure had a significant deflecting effect on the cracks. This effect allowed the composites to effectively maintain the excellent plasticity of the matrix. As a result, the core−shell SiC@HEA composites obtained superior strength and plasticity with multiple mechanisms.

Cite this article

Chong-yang LIU, Xiao-song JIANG, Hong-liang SUN, Zi-xuan WU, Liu YANG . Synergistic enhancement of strength and plasticity in CoCrFeNiMn high-entropy alloys by novel core−shell microstructure design[J]. Transactions of Nonferrous Metals Society of China, 2025 , 35(10) : 3428 -3442 . DOI: 10.1016/S1003-6326(25)66890-7

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